To make cheese glue you need quicklime or slaked lime. My understanding is that there are three types of lime commonly available:
- Garden lime is calcium carbonate CaCO3. Its just ground limestone and is available from lawn and garden suppliers. Its not useful for this purpose.
- Quicklime is calcium oxide CaO. Its made by burning limestone, and is caustic. Theophilius and Cennini use it to make cheese glue. I think its available from building suppliers for making concrete, mortar, etc.
- Slaked lime or hydrated lime or pickling lime is Ca(OH)2. Its made by mixing quicklime and water, and is less caustic but still a strong base. Its available from building supply stores, hardware stores, and in small quantities from food supply stores.
We don't have quicklime so I will visit Home Hardware and buy some slaked lime. Its less dangerous than mixing quicklime and water yourself. There are a handy list of precautions in C. M. Helm-Clark, Ph.D, Medieval Glues Up to 1600 CE (2007)
http://www.rocks4brains.com/glue.pdf (thanks Gerhard for the link).
The
Thegns of Mercia just make their own curds from unpasturized milk. I have heard of other people using fat-free cottage cheese. Gaukler's partner Barbara has made cheese glue / casein glue and I will update this post if she uses another source for the cheese.
Granules or pearls of hide glue are available from art-supply stores and woodworking stores such as Lee Valley. If you work with a lot of rawhide or parchment, you can also boil down offcuts and scrapings yourself. Cennini seemed to prefer glue from skins and cartilege of goats for his projects, modern "hide glue" is often cow-based, modern "rabbit-skin glue" is rabbit-based. Old Pliny the Elder seemed to think that the common glue used by woodworkers was cow-based, he also mentions a fish glue.
I'm not sure of the first evidence for cheese glue. C. M. Helm-Clark says Pliny mentions it, but I can't find the reference. In the 9th century, the
Mappae Clavicula mentions cheese glue. According to: Maya Heath, "A Practical Guide to Medieval Adhesives,"
https://www.scribd.com/document/3285959 ... -Adhesives
there is a description of cheese glue in a composite bow from Ancient Egypt in:
Baker, Tim, “Glue”, The Traditional Bowyer’s Bible, Volume 1, Bois d’Arc Press, Lyons & Burford, Publishers, New York, 1992, p. 203
Edit: Cheese glue is not in "Ancient Egyptian Materials and Industries" by A. Lucas and J. Harris. But casein glue is notorious for decaying, and its not a famous type of glue like collagen glue.
Edit: Eureka!
https://www.getty.edu/publications/mumm ... rt-two/16/
In our study (of round shields from the Roman city of Dura Europos), surface scrapings of paint layers and residual glue on the edge of the wood slats were analyzed with FTIR and gas chromatography/mass spectrometry (GC/MS). FTIR detected proteins in the glue sample, which indicates that animal glue was used to join the slats; however, both FTIR and GC/MS identified wax as the binding medium of the paint layers. Proteins were not detected in the paint samples.
Dr. Brandon Gassaway of the Rinehart Lab in the Department of Cellular & Molecular Physiology and the Systems Biology Institute at Yale analyzed surface scrapings of paint layers and glue from the edge of wood slats with mass spectrometry–based proteomics. In both samples, casein, β-lactoglobulin, and serum albumin were found, attesting to the presence of bovine milk.
So that is evidence for cheese glue in shields by the 3rd century CE.